Product ID:ANILINE-D5 2 MG/ML 1ML, 48788
MSDS Date:04/04/1988
FSC:6850
NIIN:00N019161
MSDS Number: BLGKX

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

ANILINE (SARA III)

CAS: 62-53-3

RTECS: BW6650000

Fraction By Weight: 0.2%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 2 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 99.8%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

OVEREXPOSURE. INCREASED SENSITIVITY OF THE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL RAT) 2524 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHALED. HARMFUL IF
SWALLOWED. LACHRIMATION. IRRITATIES SKIN. DERM, HDCH, DIZZ,
NARCOSIS, LIVER & KIDNEY DMG. SEVERAL CHRONIC INHAL STUDIES
REPORTED BY NIOSH REVEALED THAT TEST ANIMALS EXPOSED TO METHYLENE
CHLORIDE CONCENTRATIONS AS HIGH AS 10,000 PPM SHOWED SLIGHT LIVER &
KIDNEY (EFTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:GROUP 2B (IARC),
GROUP 2 (NTP)
Effects of Overexposure:HLTH HAZ:CHANGES. METHYLENE CHLORIDE IS NOT
BELIEVED TO POSE CARC RISK TO MAN WHEN HANDLED AS REC. IN RATS,
METHYLENE CHLORIDE HAS BEEN SHOWN TO PRODUCE STATISTICALLY
SIGNIFICANT INCREASE IN SALIVARY GLAND TUMORS. RESEARCH HAS
RECENTLY SHOWN THAT CH2CL2 IS METABOLIZED BY BODY TO CO & CAN
STRESS CVS THROUGH (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN:PROMPTLY
WASH WITH SOAP & LARGE VOLUMES OF WATER. REMOVE CONTAMINATED
CLOTHING. INHAL:IMMED MOVE TO FRESH AIR. GIVE O2 IF BRTHG LABORED.
IF BRTHG STO PS, GIVE ARTF RESP. GET MD. INGEST:NEVER GIVE ANYTHING
BY MOUTH TO UNCON PERS. NEVER TRY TO MAKE UNCON PERS VOMIT. DO NOT
INDUCE VOMIT. IMMED GET MD. NEVER GIVE ADRENALIN FOLLOWING
CH2CL2(SEE ING 3)

Lower Limits:12.0%
Upper Limits:19.0%
Extinguishing Media:WATER, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQIUPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN MATERIAL IS HEATED TO DECOMPOSITION:HCL & PHOSGENE.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER.
METHYLENE CHLORIDE VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN
LOW AREAS. AVOID EYE OR SKIN CONTACT.
Other Precautions:POSSIBLE CANCER HAZARD. AVOID BREATHING VAPORS. NO
SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC
WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK WITH ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:NEOPRENE GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NOT APPLICABLE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HLTH HAZ:ELEVATION OF LEVEL OF CARBOXYHEMOGLOBIN. CHLOROCARBON MATLS
HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHR
INE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE- SUSTAINING USES IN
HUMANS ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS(FP N

HCC:T4
Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-143F,-97C
Vapor Pres:349 @ 20C
Vapor Density:2.93
Spec Gravity:1.320
Evaporation Rate & Reference:0.71(ETHER=1)
Solubility in Water:2
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH ETHER LIKE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG BASES AND OXIDIZING AGENTS.
Stability Condition to Avoid:FLAMES, HOT GLOWING SURFACES OR ELECTRIC
ARCS.
Hazardous Decomposition Products:HCL & PHOSGENE.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.